Extremely thin absorber layer solar cells on zinc oxide nanorods by chemical spray
Identifieur interne : 004189 ( Main/Repository ); précédent : 004188; suivant : 004190Extremely thin absorber layer solar cells on zinc oxide nanorods by chemical spray
Auteurs : RBID : Pascal:10-0278837Descripteurs français
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Abstract
ZnOrod/In2S3/CuInS2 type ETA-cells were prepared by in-line chemical spray pyrolysis method. Effects of buffer layer thickness and ZnO nanorod length (500-1000 nm) were studied by means of SEM, I-V dependencies and EQE spectra. Conformal layer of In2S3, obtained by spray of solution with pH=4.8, effectively protects ZnO nanorods from dissolution during the spray of acidic solutions. Increasing In2S3 layer thickness reduces fluctuations of the cell output parameters, and increases Voc and FF; however, at certain thickness induces losses due to light absorption. The highest conversion efficiency 4.17% at AM1.5 was recorded from small contact area of the cell based on rods with length of 600 nm. Perspectives for further development are discussed.
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<term>Indium</term>
<term>Indium sulfide</term>
<term>Nanorod</term>
<term>Pyrolysis</term>
<term>Solar cell</term>
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<front><div type="abstract" xml:lang="en">ZnO<sub>rod</sub>
/In<sub>2</sub>
S<sub>3</sub>
/CuInS<sub>2</sub>
type ETA-cells were prepared by in-line chemical spray pyrolysis method. Effects of buffer layer thickness and ZnO nanorod length (500-1000 nm) were studied by means of SEM, I-V dependencies and EQE spectra. Conformal layer of In<sub>2</sub>
S<sub>3</sub>
, obtained by spray of solution with pH=4.8, effectively protects ZnO nanorods from dissolution during the spray of acidic solutions. Increasing In<sub>2</sub>
S<sub>3 </sub>
layer thickness reduces fluctuations of the cell output parameters, and increases V<sub>oc</sub>
and FF; however, at certain thickness induces losses due to light absorption. The highest conversion efficiency 4.17% at AM1.5 was recorded from small contact area of the cell based on rods with length of 600 nm. Perspectives for further development are discussed.</div>
</front>
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/CuInS<sub>2</sub>
type ETA-cells were prepared by in-line chemical spray pyrolysis method. Effects of buffer layer thickness and ZnO nanorod length (500-1000 nm) were studied by means of SEM, I-V dependencies and EQE spectra. Conformal layer of In<sub>2</sub>
S<sub>3</sub>
, obtained by spray of solution with pH=4.8, effectively protects ZnO nanorods from dissolution during the spray of acidic solutions. Increasing In<sub>2</sub>
S<sub>3 </sub>
layer thickness reduces fluctuations of the cell output parameters, and increases V<sub>oc</sub>
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